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11.
Abstract— Based on recent progress in simulating space weathering on asteroids using pulse‐laser irradiation onto olivine and orthopyroxene samples, detailed analyses of two of the A and R type asteroid reflectance spectra have been performed using reflectance spectra of laser‐treated samples. The visible‐near‐infrared spectrum of olivine is more altered than that of pyroxene at the same pulse‐laser energy, suggesting that olivine weathers more rapidly than orthopyroxene in space. The same trend can be detected from reflectance spectra of the asteroids, where the more olivine an asteroid has, the redder its 1 μm band continuum can become. Comparison of the 1 μm band continuum slope and the 2/1 μm band area ratio between the asteroids and olivine and pyroxene samples (including the laser‐treated ones) suggests that asteroids may be limited in the degree of space weathering they can exhibit, possibly due to the short life of their surface regolith. Their pyroxenes may also have a limited chemical composition range. Fitting the visible continuum shape and other parts of the spectra (especially the 2μm part) has been impossible with any combination of common rock‐forming minerals such as silicates and metallic irons. However, this study shows, for the first time, excellent fits of reflectance spectra of an A asteroid (Aeternitas) and an R asteroid (Dembowska), including their visible spectral curves, band depths and shapes, and overall continuum shapes. Our results provide estimates that Aeternitas consists of 2% fresh olivine, 93% space‐weathered olivine, 1% space‐weathered orthopyroxene, and 4% chromite, and that Dembowska consists of 1% fresh olivine, 55% space‐weathered olivine, and 44% space‐weathered orthopyroxene. These results suggest that space weathering effects maybe important to the interpretation of asteroid reflectance spectra, even those with deep silicate absorption bands. Modified Gaussian model deconvolutions of the laser‐irradiated olivine samples show that their identity as olivine remained. The most recent submicroscopic mineralogical analyses have revealed that the laser‐irradiated olivine samples contain nanophase iron particles similar to those in space‐weathered lunar samples.  相似文献   
12.
This paper describes petrologic and geochemical characteristics of intrusive rocks associated with porphyry copper deposits in south-eastern Mindanao, the Philippines, where the Kingking deposit is located. Intrusive rocks at the Kingking deposit, are classified into biotite-bearing diorite porphyry, hornblende diorite porphyry and diorite porphyry. Intrusive rocks in other areas in south-eastern Mindanao, including Batoto, Bukal, Maragusan, Masara, Amacan and Sumlog, are hornblende diorite porphyry and hornblende quartz diorite. They are adakitic in Sr/Y-Y diagram, but not in La/Yb-Yb diagram due to relatively low REE contents. The magmas are oxidizing as suggested by the high XMg of mafic silicate phenocrysts and SO3 contents of microphenocrystic apatite. An Oligocene-Miocene diorite intrusive complex formed by calc-alkaline, hydrous, oxidizing magma is considered to be associated with porphyry-type copper-gold mineralization.  相似文献   
13.
The Kingking deposit is a gold‐rich porphyry copper deposit and the southernmost deposit at the eastern Mindanao mineralized belt, Philippines. It is underlain by Cretaceous–Paleogene sedimentary and volcanic rocks that are intruded by mineralized Miocene diorite porphyries and by barren Miocene–Pliocene dacite and diorite porphyries. The main alteration zones in the deposit are the inner potassic zone and the outer propylitic zone. The biotite‐bearing diorite and hornblende diorite porphyries are the primary host rocks of mineralization. Two dominant copper minerals, bornite and chalcopyrite, which usually occur as fracture fillings, are associated with fine crystalline quartz veinlet stockworks in the mineralized diorites. Minor secondary covellite, chalcocite and digenite are also observed. The primary Cu‐Fe sulfide phases initially deposited from ore fluids consisted of bornite solid solution (bnss) and intermediate solid solution (iss), which decomposed to form the bornite and chalcopyrite. Peculiar bornite pods that are different from dissemination and are associated with volcanic rock xenoliths in biotite‐bearing diorite porphyry are noted in a drill hole. These pods of bornite are not associated with quartz veinlet stockworks. Fluid inclusion analyses show three types of inclusions contained in Kingking samples: two‐phase fluid‐rich and vapor‐rich inclusions and polyphase hypersaline inclusions from porphyry‐type quartz veinlet stockworks. The liquid–vapor homogenization temperatures (TH) and the dissolution temperature of halite daughter crystals (TM) from the polyphase hypersaline inclusions predominantly range from 400°C up to >500°C. The wide range of TH and TM may be due to heterogeneous trapping of variable ratios of vapor and brine. For some inclusions, TH > TM and in some cases, TH < TM, indicating that some of the brine was supersaturated or saturated with NaCl at the time of entrapment. Calculated salinity of the polyphase hypersaline inclusions ranges from 40 to 60% NaCl equivalent. Temperature and vapor pressure of mineralized fluid were estimated to be 400°C and 16 MPa.  相似文献   
14.
The electrical conductivity of (Mg0.93Fe0.07)SiO3 ilmenite was measured at temperatures of 500–1,200 K and pressures of 25–35 GPa in a Kawai-type multi-anvil apparatus equipped with sintered diamond anvils. In order to verify the reliability of this study, the electrical conductivity of (Mg0.93Fe0.07)SiO3 perovskite was also measured at temperatures of 500–1,400 K and pressures of 30–35 GPa. The pressure calibration was carried out using in situ X-ray diffraction of MgO as pressure marker. The oxidation conditions of the samples were controlled by the Fe disk. The activation energy at zero pressure and activation volume for ilmenite are 0.82(6) eV and −1.5(2) cm3/mol, respectively. Those for perovskite were 0.5(1) eV and −0.4(4) cm3/mol, respectively, which are in agreement with the experimental results reported previously. It is concluded that ilmenite conductivity has a large pressure dependence in the investigated P–T range.  相似文献   
15.
Chemical analysis of biotite in representative granitic rocks in Japan shows that the total Al (TAl) content changes with the metal type of the accompanying hydrothermal ore deposits and increases in the following order: Pb‐Zn and Mo deposits < Cu‐Fe and Sn deposits < W deposits < non‐mineralized granitic rocks. The TAl content of biotite in granitic rocks may be a useful indicator for distinguishing between mineralized and non‐mineralized granitic rocks. A good positive correlation is seen between the TAl content of biotite and the solidification pressure of the granitic rocks estimated by sphalerite and hornblende geobarometers and the mineral assemblages of the surrounding rocks. These facts suggest that the TAl content of biotite can be used to estimate the solidification pressure (P) of the granitic rocks. The following empirical equation was obtained: where TAl designates the total Al content in biotite on the basis O = 22. According to the obtained biotite geobarometer, it is estimated that Pb‐Zn and Mo deposits were formed at pressures below 1 kb, Cu‐Fe and Sn deposits at 1–2 kb, W deposits at 2–3 kb and non‐mineralized granitic rocks were solidified at pressures above 3 kb.  相似文献   
16.
The Okinoshima Formation crops out on Okinoshima Island and comprises a thick sequence (> 200 m) of pyroclastic rocks and alternating beds of sandstone and mudstone. Because Okinoshima Island is located between Honshu and Tsushima Island, the Okinoshima Formation potentially provides an important record of volcanism during the opening of the Japan Sea in northwest Kyushu, as well as a record of the formation of the present Genkai Sea region. In consideration of the lack of previous geochronological work, dating (fission‐track and U–Pb) of igneous zircons extracted from the Okinoshima Formation were undertaken and studied the clay mineral alteration in the pyroclastic material in order to reveal its thermal history. These data are used to constrain the age of the Okinoshima Formation and the present Genkai Sea region. Our results show that no thermal event has reset the fission‐track age after deposition of the pyroclastic rocks, and that the Okinoshima Formation was deposited at 16.2 Ma. The present Genkai Sea region is a deep‐sea basin, and its formation at 16.2 Ma was accompanied by submarine volcanism and rapid subsidence that marked the climactic stage of Japan Sea formation. After 16 Ma, the tectonic setting of the present Genkai Sea region changed from one of extension (related to the formation of the Japan Sea) to one of compression, with uplift occurring under the influence of the clockwise rotation of southwest Japan. Consequently, after 16 Ma the present Genkai Sea region became isolated from the forming processes of the Japan Sea.  相似文献   
17.
On the sub-kilometer S-type asteroid, 25143 Itokawa, some boulders on rough terrains seem to be exposed without any powdery material covering. Based on surface morphological features, there are two major types of boulders: one has rounded edges and corners (rounded boulders), while the other has angular edges and corners (angular boulders). The surface features of the rounded boulders suggest that they have hardness heterogeneity and that some may be breccias. The angular boulders appear to be more resistant to impact disruption than the rounded ones, which may be due to a difference in lithology. The major constituents of Itokawa may be LL chondrite-like brecciated lithology (rounded boulders) along with a remarkable number of boulders suggesting that lithology is atypical among LL chondrites (angular boulders). Some of both types of boulders contain intersecting and stepped planar foliations. Comparison with meteorite ALH76009 suggests that the planar foliations may be marks where rocks were torn apart. As lithified breccias cannot be formed on present-day sub-kilometer-sized Itokawa, it is reasonable that boulders with various lithologies on Itokawa were formed on its large ancestor(s). The rubble-pile structure of Itokawa suggested by its low density (∼1.9 g/cm3) indicates that boulders on Itokawa are reassembled fragments formed by catastrophic disruption of large ancestor(s).  相似文献   
18.
At the Kingking porphyry copper-gold deposit, Compostela Valley, south-eastern Mindanao, Philippines, bornite pods occur in the brecciated parts in the biotite diorite porphyry, together with the volcanic rock and diorite fragments without associated stockworks of quartz veinlets. These pods are generally elongated in shape and measure several centimeters across their longest axes. They are composed of bornite and chalcopyrite with traces of calaverite. The δ34S of bornite and subordinate chalcopyrite of bornite pods ranging from −2.2‰ to +0.1‰ are similar to the δ34S of sulfides associated with quartz veinlets such as bornite and chalcopyrite ranging from −4.7‰ to ±0.0‰. This suggests that the ultimate source of sulfur is identical for bornite pods and sulfides associated with quartz veinlets. Bornite pods are associated with volcanic rock and dioritic fragments in the brecciated portion of the biotite diorite porphyry. It was observed that some dioritic fragments contain quartz veinlets, which may indicate an earlier episode of mineralization. Fragments of the earlier dioritic intrusive rocks and the volcanic rocks, together with the sulfides were incorporated into the biotite diorite porphyry magma. A molten sulfide is possible for the composition between bornite and intermediate solid solution at ∼800°C. The sulfides from the earlier dioritic intrusive rocks in the molten state were segregated and then eventually coalesce to form the bornite pods in the brecciated section of the biotite diorite porphyry.  相似文献   
19.
The occurrence of water ponding on soil surfaces during and after heavy rainfall produces surface run‐off or surface water accumulation in low‐lying areas, which might reduce the water supply to soils and result in a reduction of the soil water that plants can use, especially in arid climates. On Mongolian rangeland, we observed ponded water on the surface of a specific soil condition subjected to a heavy rainfall of 30 mm/hr. By contrast, ponded water was not observed for the same type of soil where livestock grazing had been removed for 6–8 years via a fence or for nearby soil containing less clay. We measured the infiltration rate (the saturated hydraulic conductivity of the surface soil, Ks) of the three sites by applying ponded water on the soil surface (an intake rate test). The results showed that Ks in the rangeland was lower than the rainfall intensity in the site where water ponded on the soil surface; however, Ks of the soil inside of the fence has recovered to 3 times that of the soil outside of the fence to exceed the rainfall intensity. Heavy rainfall that exceeds the infiltration rate occurs several times a year at the livestock grazing site where we observed ponded water. Slight water repellency of the soil reduces rain infiltration to increase the possibility of surface ponding for the soil.  相似文献   
20.
Martian meteorite chip samples stored at the National Institute of Polar Research (NIPR) have been studied by a visible and near-infrared (VNIR) spectrometer. Measured spots are about 3 × 2 mm in size, which are clearly marked on photographs of the meteorite chips. Rock types and approximate mineral compositions of studied meteorites have been identified or obtained through this spectral survey with no sample preparation required. This study demonstrates that this kind of spectral survey is effective in classifying and describing Marian meteorites, and that such a VNIR spectrometer on a Mars rover would be useful for identifying these kinds of unaltered Mars rocks. Further studies which utilize a smaller spot size are desired for improving the accuracy of identifying the clasts and mineral phases in the rocks.  相似文献   
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